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Several milder methods exist to produce ethers. Nucleophilic displacement of alkyl halides by alkoxides. This reaction is called the Williamson ether synthesis.
It involves treatment of a parent alcohol with a strong base to form the alkoxide, followed by addition of an appropriate aliphatic compound bearing a suitable leaving group R—X.
Suitable leaving groups X include iodide , bromide , or sulfonates. This method usually does not work well for aryl halides e.
Likewise, this method only gives the best yields for primary halides. Secondary and tertiary halides are prone to undergo E2 elimination on exposure to the basic alkoxide anion used in the reaction due to steric hindrance from the large alkyl groups.
In a related reaction, alkyl halides undergo nucleophilic displacement by phenoxides. The R—X cannot be used to react with the alcohol.
However phenols can be used to replace the alcohol while maintaining the alkyl halide. Since phenols are acidic, they readily react with a strong base like sodium hydroxide to form phenoxide ions.
The phenoxide ion will then substitute the —X group in the alkyl halide, forming an ether with an aryl group attached to it in a reaction with an S N 2 mechanism.
The Ullmann condensation is similar to the Williamson method except that the substrate is an aryl halide. Such reactions generally require a catalyst, such as copper.
Acid catalysis is required for this reaction. Often, mercury trifluoroacetate Hg OCOCF 3 2 is used as a catalyst for the reaction generating an ether with Markovnikov regiochemistry.
Using similar reactions, tetrahydropyranyl ethers are used as protective groups for alcohols. Epoxides are typically prepared by oxidation of alkenes.
The most important epoxide in terms of industrial scale is ethylene oxide, which is produced by oxidation of ethylene with oxygen.
Other epoxides are produced by one of two routes:. From Wikipedia, the free encyclopedia. Class of organic compounds.
For the substance whose common name is ether, see Diethyl ether. For other uses of ether or aether, see Aether. This article needs additional citations for verification.
Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.
Structure of the polymeric diethyl ether peroxide. See also: Ether cleavage. Main article: epoxide. McOmie and D. West Organic Syntheses.
Cambridge University Press. Organic chemistry. Oxford University Press. Functional groups. Phosphonate Phosphonous.
Selenol Selenonic acid Seleninic acid Selenenic acid Selone. Tellurol Telluroketone. Isothiocyanate Phosphoramide Sulfenyl chloride Sulfonamide Thiocyanate.
See also chemical classification chemical nomenclature inorganic organic. Categories : Ethers Functional groups Impression material. But Hitler did not want such a stadium to serve merely as a centre for German athletic sport.
The restored Panathenaic Stadium had been used for the Summer Olympics and the Intercalated Games , held out of series. The small village of Achtel in Hirschbach, Bavaria is the site of a sports grandstand constructed as a prototype for part of the Deutsches Stadion.
It was never used, and is now in a state of disrepair. From Wikipedia, the free encyclopedia. Redirected from Deutsche Stadion.
Spiegel Online. Der Spiegel. Retrieved Namespaces Article Talk. Now this will let you take the next steps to becoming successful.
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